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Old 11-18-06, 09:39 AM   #1
howard coleman
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AI Injectants... Scientific Properties Comparison

it really is pretty simple.... comparing water to alcohol to a mix. all the work has been done, there really isn't any conjecture except in some people's minds. the physical properties differences dictate what each is going to do and not do for you and your motor.

each injectant based on it's properties has it's place. yes, if you are pursuing a particular objective one might be better than the other.

this thread is NOT a place to argue mine is better than yours. it is a place to get the facts and then move forward.

the primary principle of the AI Section is:

run water

run alcohol

run a mix.

but run something or fry your motor.

that said, i will be posting a physical properties comparison during the next week and hope it clears away lots of part truths that fly around out there in cyberspace.

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Old 11-18-06, 12:16 PM   #2
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Here's some links for reference:

http://www.engineeringtoolbox.com/sp...ids-d_151.html

http://www.engineeringtoolbox.com/me...ter-d_987.html

http://www.geistware.com/rcmodeling/...el_cooling.htm

http://www.distill.com/materialsafety/msds-eu.html

http://www.methanol.org/pdf/MethanolMSDS.pdf
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Old 12-15-06, 02:28 AM   #3
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what happened to next week?
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Old 12-15-06, 02:58 AM   #4
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From what I read on another thread, Howards write up on this is about 25 pages at the moment so hes busy doing some editing
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Old 07-13-07, 04:02 PM   #5
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So what happened to this??
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Old 10-18-07, 03:24 PM   #6
Barry Bordes
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Quote:
Originally Posted by Viking War Hammer View Post
Typical gasoline Thermal energy 19,000 BTU/lb max power fuel air mixture 12.5:1
Typical E85 Thermal energy 13,475 BTU/lb max power fuel air mixture 6.975:1
Typical ethanol Thermal energy 12,500 BTU/lb 6.429:1

If you are consuming 100 lbs of air, lets see how much fuel energy you release for each of these fuels.
100/12.5 = 8 lbs of gasoline @ 19,000 BTU/lb = 152,000 BTU
100/6.975 = 14.337 lbs of E85 @ 13,475 BTU/lb = 193,189.9 BTU = 127% more heat energy
100/6.429 = 15.555 lbs of Ethanol @ 12,500 BTU/lb = 194431.5 BTU = 128.9% more heat energy


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Old 10-18-07, 03:47 PM   #7
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Great info. Where's the source documentation?

B
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Old 10-18-07, 07:49 PM   #8
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apologies to all for the brief delay...

the primary reason i didn't follow thru was about the time i started the thread the AI wars were escalating and i just decided to let things cool a bit rather than stir the injectant pot.

ideally this thread should not be an either or (water or alcohol) but a resource as to what makes each injectant a bit different.

both have a legitimate place in the AI space.

that said, just a couple of comments...

you really see differing numbers on alcohol's octane. one of the problems is that octane is rated at a specific temperature. alcohol cools so much that there is no way it can be rated at that temperature so we get guesses.

i will say this... it has been my experience thru lots of road testing and 3 dyno sessions that the more alcohol the better. i will be shortly moving from 1200 CC/Min to 1600 CC/Min at peak torque/peak boost.

one of the more interesting considerations is the autoignition temperature of alcohol... to be clear, autoignition is simply the temp where a substance starts burning.

this is highly relevant w the rotary relative to preignition/knock.

gasoline, including racegas, auto-ignites at 660 degrees F.

alcohol, (methanol, ethanol and isopropyl) ignite at 858 degrees F!


that's alot of additional protection against bad things...

i'll be back with more.

any people feel free to add here and that includes the waterites.

hc
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Old 10-26-07, 01:30 PM   #9
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i was checking out Boostcreeps.com and stumbled on a thread talking about the hi value of low IATs (intake air temperatures)...

http://www.boostcreeps.com/phpBB/viewtopic.php?t=501

"I was tuning a car on the dyno that had high IATs. We sprayed the IC with some nitrous to cool it down, and this dropped the temp 10degF, and the car picked up 14whp!! Same timing, same AF, same boost ,etc (replete with AEM logs to substantiate this claim). This was on a car making mid-high 500s. Quite a significant bump! And this car had about another 30degF left to go before the temps were 'ideal' (i.e. 10degF above ambient)... so in theory it could pick up 45whp from just a better FMIC! Quite significant. So IAT reduction might be a worthwhile point on those of us running undersized FMICs. While the race gas can keep the detonation at bay, the gains from increased air density seem quite significant."

of course we know that the primary deal w lower IATs is more oxygen molecules per volume. and when you are talking oxygen nothing beats alcohol, or methanol specifically.

meth is 49% oxygen by weight
ethanol is 34% oxygen by weight.
gasoline is zero% oxygen.

as to cooling:

meth is 1.154 MJ/Kg
eth is .913
gasoline is .297


Meth is the winner.... lots of oxygen and lots of cooling.

hc
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Old 10-26-07, 06:04 PM   #10
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Very similar to that^^^, I read an article where someone was using a dual loop intercooler sprayer that looked like a figure 8 on thier drag civic and it picked up 60 horses. Of course they were also spraying nitrous onto the core. I'll see if I can find it.


EDIT- Here it is http://www.hondatuningmagazine.com/t...est/index.html
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Old 11-29-07, 07:57 AM   #11
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We seem to have missed the comparison to water.
Taken from engineeringtoolbox http://www.engineeringtoolbox.com/

Product Latent Heat of Evaporation
(kJ/kg) (Btu/lb)
Acetone 518 223
Alcohol 896 385
Alcohol, ethyl (ethanol) 846 364
Alcohol, methyl (methanol) 1100 473
Alcohol, propyl 779 340
Benzene 390 168
Heptane 318 137
Hexane 365 157
Kerosene 251 108
Propane 428 184
Toluene 351 151
Water 2257 970

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Old 03-10-08, 04:59 PM   #12
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i hate to bring this thread back from a few months but it seems that barry is showing the latent heat for vaporization of water is twice that of methanol and second highest enthalpy to ammonia.. which is due to hydrogen bonding.. and i understand that the more oxygen the better for keeping autoignition down but im just wondering the results of water compared to alcohol numbers-wise.. if anyone can show some quantifiable data that would be much appreciated thank you

edit: i realize the ammonia thing isnt in barrys post i was just throwing it out there
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Old 11-02-08, 06:42 PM   #13
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I think we're missing the numbers for the specific heat of each fuel in both liquid and air form. I believe latent heat of vaporization numbers are measured at the boiling point, which can skew things if you're spraying a liquid below the boiling point. Then you need to figure out how much energy it takes to heat it up to boiling first, based on the specific heat of the liquid and the change in temperature. And this all might vary with pressure too, I don't remember.

So what we really need is to calculate in then is X kJ of heat absorbed per kg of fuel when the air temperature right outside the intake is 70F, 80F, 90F, 100F, 110F and 120F. That would help provide the most direct comparison between the cooling properties of each. And it would be useful if you're looking to replace x grams of gasoline with y grams of water or with z grams of alcohol and need to get an estimate of what y or z should be. There may be other factors to consider as well, but this should be what matters in terms of preventing detonation.
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Old 01-13-09, 05:15 AM   #14
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I always wanted to do a 50/50 mix of water and Methanol, but it's too time consuming for me to play chemist and get the mix right every time I fill up. Especially when you drive alot. Rather not worry about it and just use 100% Meth. It smells good too when you smoke the car behind you. *Burning Eyes!*
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Old 01-16-09, 06:10 AM   #15
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Very similar to that^^^, I read an article where someone was using a dual loop intercooler sprayer that looked like a figure 8 on thier drag civic and it picked up 60 horses. Of course they were also spraying nitrous onto the core. I'll see if I can find it.


EDIT- Here it is http://www.hondatuningmagazine.com/t...est/index.html
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Old 02-18-09, 09:33 AM   #16
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OK, my little contribution of what i have managed to glean elsewhere


i fill my rx7 with straight propane
despite the slight BTU losses in volume to blended LPG and petrol
its octane is almost unbeatable, its pound for pound, kilo for kilo comparable in energy to petrol
- and its pump quality/purity assured


-this is an amalgam from my other posts elsewhere-


footnote --

RON or MON or AKI?

in the US ( AKI ) and aus/Europe ( RON ) , different methods are used

what is US 87 octane ( AKI ) is European 91 ( RON )
or aussie normal unleaded
is actually RON 91, 86.75 AKI and 82.5 MON

and conversely ,,
what we in australia call PULP
RON 95 , AKI 91 , MON 85

and PULP 98
RON 98 , AKI 94, MON 88

and blended LPG is
RON 100 , AKI around 97, MON 92
MINIMUM
STILL SLIGHTLY BETTER THAN THE BEST PULP
even at 50% butane blended into 50% propane

and propane is
RON 115 , AKI 110, MON 103
and 91,547 BTUs versus 116,000 BTUs per gallon for gasoline/petroleum
-Methanol contains only 57,000 BTUs per gallon, which is half that of gasoline
( volume comparison)

But on a pound per pound basis, propane delivers almost the same energy as gasoline (21,591 BTUs)
( mass basis )




AKI - numbers ( averaged RON and MON )

hexadecane < -30
n-octane -10
n-heptane 0
diesel fuel 15–25
2-methylheptane 23
n-hexane 25
2-methylhexane 44
hydrogen* RON > 130; MON very low[5]
1-heptene 60
n-pentane 62
1-pentene 84
n-butanol 87
E10 gasoline 87–93
n-butane 91
t-butanol 97
cyclohexane 97
iso-octane 100
benzene 101
E85 gasoline 105
methane 107
ethane 108
propane 110
methanol 113
toluene 114
ethanol 116
xylene 117


here are all the fuel additive octanes -
Quote:
15% n-paraffins

------------------ RON: MON: BP : d: AIT
n-butane 113 : 114 : -0.5: gas : 370
n-pentane 62 : 66 : 35 : 0.626 : 260
n-hexane 19 : 22 : 69 : 0.659 : 225
n-heptane (0:0 by definition) 0 : 0 : 98 : 0.684 : 225
n-octane -18 : -16 : 126 : 0.703 : 220
( you would not want to have the following alkanes in gasoline,
so you would never blend kerosine with gasoline )
n-decane -41 : -38 : 174 : 0.730 : 210
n-dodecane -88 : -90 : 216 : 0.750 : 204
n-tetradecane -90 : -99 : 253 : 0.763 : 200


30% iso-paraffins

2-methylpropane 122 : 120 : -12 : gas : 460
2-methylbutane 100 : 104 : 28 : 0.620 : 420
2-methylpentane 82 : 78 : 62 : 0.653 : 306
3-methylpentane 86 : 80 : 64 : 0.664 : -
2-methylhexane 40 : 42 : 90 : 0.679 :
3-methylhexane 56 : 57 : 91 : 0.687 :
2,2-dimethylpentane 89 : 93 : 79 : 0.674 :
2,2,3-trimethylbutane 112 : 112 : 81 : 0.690 : 420
2,2,4-trimethylpentane 100 : 100 : 98 : 0.692 : 415
( 100:100 by definition )

12% cycloparaffins

cyclopentane 141 : 141 : 50 : 0.751 : 380
methylcyclopentane 107 : 99 : 72 : 0.749 :
cyclohexane 110 : 97 : 81 : 0.779 : 245
methylcyclohexane 104 : 84 : 101 : 0.770 : 250

35% aromatics

benzene 98 : 91 : 80 : 0.874 : 560
toluene 124 : 112 : 111 : 0.867 : 480
ethyl benzene 124 : 107 : 136 : 0.867 : 430
meta-xylene 162 : 124 : 138 : 0.868 : 463
para-xylene 155 : 126 : 138 : 0.866 : 530
ortho-xylene 126 : 102 : 144 : 0.870 : 530
3-ethyltoluene 162 : 138 : 158 : 0.865 :
1,3,5-trimethylbenzene 170 : 136 : 163 : 0.864 :
1,2,4-trimethylbenzene 148 : 124 : 168 : 0.889 :

8% olefins

2-pentene 154 : 138 : 37 : 0.649 :
2-methylbutene-2 176 : 140 : 36 : 0.662 :
2-methylpentene-2 159 : 148 : 67 : 0.690 :
cyclopentene 171 : 126 : 44 : 0.774 :
( the following olefins are not present in significant amounts
in gasoline, but have some of the highest blending octanes )
1-methylcyclopentene 184 : 146 : 75 : 0.780 :
1,3 cyclopentadiene 218 : 149 : 42 : 0.805 :
dicyclopentadiene 229 : 167 : 170 : 1.071 :

Oxygenates

methanol 133 : 105 : 65 : 0.796 : 385
ethanol 129 : 102 : 78 : 0.794 : 365
iso propyl alcohol 118 : 98 : 82 : 0.790 : 399
methyl tertiary butyl ether 116 : 103 : 55 : 0.745 :
ethyl tertiary butyl ether 118 : 102 : 72 : 0.745 :
tertiary amyl methyl ether 111 : 98 : 86 : 0.776 :
where-
RON is the knock test at 600 rpm and 40 celcius air temps
MON is a test on same engine at 900 rpm and 150 celsius air temps
BP is the boiling point in celsius
AIT is auto ignition temperature
d is fuel density compared to 1 L/ 1 KG of pure water


--- you can see why in the past i was keen to use toluene and xylene and even acetone as minor fuel additives on drag day

Last edited by bumpstart; 02-18-09 at 09:37 AM. Reason: typo corrected
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Old 02-18-09, 09:54 AM   #17
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these are the ricardo scale results
( anti pre-ignition index, as different from anti knock index )
where iso octane = 100, cyclo hexane = 0

-There is no direct correlation between antiknock ability and preignition
tendency

paraffins 50-100
benzene 26
toluene 93
xylene >100
cyclopentane 70
di-isobutylene 64
hexene-2 -26
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